Heat up your oven to 350, turn it off put glove in oven for 5 minutes. Take it out and beat the heck out of it until it comes back to regular temp. repeat process about 5x right away and it will be loose and broken in.
THIS but, I also apply a light coat of EVOO each time it comes out of the oven ... PLUS, being the forgetful often easily distracted person I am, I set the timer on the oven and on my phone as a back up to make sure the mitt does not end up resembling a smoldering eggplant parm ... just sayin'
*edited to say I also use a slightly lower temperature
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